Domain-swapped cytochrome cb 562 dimer and its nanocage encapsulating a Zn–SO4 cluster in the internal cavity† †Electronic supplementary information (ESI) available: Experimental procedure, size exclusion chromatogram, DSC thermogram, protein structure and statistics of data collection. See DOI: 10.1039/c5sc02428e Click here for additional data file.

Domain-swapped cytochrome cb562 dimer and its nanocage encapsulating a Zn-SO4 cluster in the internal cavity.

Protein nanostructures have been gaining in interest, along with developments in new methods for construction of novel nanostructures. We have previously shown that c-type cytochromes and myoglobin form oligomers by domain swapping. Herein, we show that a four-helix bundle protein cyt cb562, with the cyt b562 heme attached to the protein moiety by two Cys residues insertion, forms a domain-swap...

Dynamic induction of enantiomeric excess from a prochiral azobenzene dimer under circularly polarized light† †Electronic supplementary information (ESI) available: Synthesis, 1H NMR spectra, 13C NMR spectra, UV absorption plots, HPLC traces, and CD spectra of the compounds; crystallographic information files. CCDC 1003754. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc01993h Click here for additional data file. Click here for additional data file.

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization† †Electronic supplementary information (ESI) available: Experimental section, full characterization of compounds in solution and in the solid state, polymerization and polymer analysis, details of reactivity, tacticity determination, DSC, PGSE studies, in situ polymerization studies. CCDC 1062730–1062733 and 1062738. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01584g Click here for additional data file. Click here for additional data file.

Halogen bonded Borromean networks by design: topology invariance and metric tuning in a library of multi-component systems† †Electronic supplementary information (ESI) available: Materials and methods, NMR, DSC, powder and single crystal X-ray data. CCDC 1505909–1505934. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04478f Click here for additional data file. Click here for additional data file. Click here for additional data file.

Laboratory of Nanostructured Fluorinate Chemistry, Materials, and Chemical Eng Milano, Via L. Mancinelli 7, 20131 Milano, VTT-Technical Research Centre of Finland, † Electronic supplementary information ( NMR, DSC, powder and single crystal XESI and crystallographic data in CIF 10.1039/c6sc04478f ‡ Present address: Laboratory of Nanomaterials, Université Libre de Bru Bruxelles, Belgium. Cite th...

Versatile telluracycle synthesis via the sequential electrophilic telluration of C(sp2)–Zn and C(sp2)–H bonds† †Electronic supplementary information (ESI) available. CCDC 1523262–1523264. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01162h Click here for additional data file. Click here for additional data file.